Hydrocarbon binding inside a hexameric pyrogallol[4]arene capsule

被引:65
作者
Palmer, LC
Rebek, J
机构
[1] Scripps Res Inst, Skaggs Inst Chem Biol, La Jolla, CA 92037 USA
[2] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA
关键词
D O I
10.1021/ol047673x
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Pyrogallol[4]arene forms discrete hexameric capsules in neat normal, branched, and cyclic alkanes. These hydrocarbon guests fill the available space and show chemical exchange that is slow on the NMR time scale.
引用
收藏
页码:787 / 789
页数:3
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