Efficient catalytic oxidation of primary and secondary alcohols using a non-heme dinuclear iron complex

被引:36
作者
Ligtenbarg, AGJ
Oosting, P
Roelfes, G
La Crois, RM
Lutz, M
Spek, AL
Hage, R
Feringa, BL
机构
[1] Univ Groningen, Dept Organ & Mol Inorgan Chem, NL-9747 AG Groningen, Netherlands
[2] Univ Utrecht, Dept Crystal & Struct Chem, NL-3584 CH Utrecht, Netherlands
关键词
D O I
10.1039/b009368h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel mu -oxo diiron(iii) complex is capable of fast and selective oxidation of primary and secondary alcohols in the presence of H2O2 and a remarkable increase in reaction rate is achieved by addition of 1 eq. of CF3SO3H.
引用
收藏
页码:385 / 386
页数:2
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