Highly Stable Porous Polymer Networks with Exceptionally High Gas-Uptake Capacities

被引：542

作者：

Yuan, Daqiang ^{[1
]}

Lu, Weigang ^{[1
]}

Zhao, Dan ^{[2
]}

Zhou, Hong-Cai ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

[2] Argonne Natl Lab, Chem Sci & Engn Div, Argonne, IL 60439 USA

来源：

ADVANCED MATERIALS | 2011年 / 23卷 / 32期

基金：

美国国家科学基金会;

关键词：

METAL-ORGANIC FRAMEWORKS; HIGH-SURFACE-AREA; POROSITY; STORAGE;

D O I：

10.1002/adma.201101759

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Highly stable porous polymer networks (PPNs) are synthesized through a Yamamoto homocoupling reaction between tetrahedral monomers. Among those polymers, PPN-4 shows exceptionally high Langmuir surface area of 10063 m(2) g(-1) (SA(BET): 6461 m(2) g(-1)). It also exhibits ultra high hydrogen, methane, and carbon dioxide storage capacities. These properties make it a perfect adsorbent for clean energy applications.

引用

页码：3723 / +

页数：4

共 22 条

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