Metallathiirenes. 5. Bis- and tris(methimazolyl)borato thiocarbamoyl complexes of molybdenum(II)

被引：46

作者：

Foreman, MRS

Hill, AF ^{[1
]}

Tshabang, N

White, AJP

Williams, DJ

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

[2] Australian Natl Univ, Inst Adv Studies, Res Sch Chem, Canberra, ACT, Australia

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 26期

关键词：

D O I：

10.1021/om030584o

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thiocarbamoyl complexes [Mo(eta(2)-SCNMe2)-(CO)(2){HnB(mt)(4-n)}] (n = 1, 2) are obtained from the reactions of [Mo(eta(2)-SCNMe2)Cl(CO)(2)(tmeda)]andNa[HnB(mt)(4-n)] or via reactions of the salts Na[Mo(CO)(2+n){HnB(mt)(4-n)}] with Me2NCSCl. For n = 2, the complex displays agostic B-H-Mo coordination in both solution and the solid state.

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页码：5593 / 5596

页数：4

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