Metallathiirenes. 5. Bis- and tris(methimazolyl)borato thiocarbamoyl complexes of molybdenum(II)

被引:46
作者
Foreman, MRS
Hill, AF [1 ]
Tshabang, N
White, AJP
Williams, DJ
机构
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England
[2] Australian Natl Univ, Inst Adv Studies, Res Sch Chem, Canberra, ACT, Australia
关键词
D O I
10.1021/om030584o
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Thiocarbamoyl complexes [Mo(eta(2)-SCNMe2)-(CO)(2){HnB(mt)(4-n)}] (n = 1, 2) are obtained from the reactions of [Mo(eta(2)-SCNMe2)Cl(CO)(2)(tmeda)]andNa[HnB(mt)(4-n)] or via reactions of the salts Na[Mo(CO)(2+n){HnB(mt)(4-n)}] with Me2NCSCl. For n = 2, the complex displays agostic B-H-Mo coordination in both solution and the solid state.
引用
收藏
页码:5593 / 5596
页数:4
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