Rotational-resolved pulsed field ionization photoelectron bands for H2+(X2Σg+, v+ = 0, 2, 9, and 11)

被引：40

作者：

Stimson, S

Chen, YJ

Evans, M

Liao, CL

Ng, CY ^{[1
]}

Hsu, CW

Heimann, P

机构：

[1] Iowa State Univ, US DOE, Ames Lab, Ames, IA 50011 USA

[2] Iowa State Univ, Dept Chem, Ames, IA 50011 USA

[3] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Chem Sci, Berkeley, CA 94720 USA

[4] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Accelerator & Fus Res, Adv Light Source, Berkeley, CA 94720 USA

来源：

CHEMICAL PHYSICS LETTERS | 1998年 / 289卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(98)00412-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We present here the assignment and simulation of rotational transitions for the H-2(+) (X-2 Sigma(g)(+), upsilon(+) = 0,2,9 and 11) vibronic bands using the Buckingham-Orr-Sichel (BOS) model. The simulation shows that perturbation of PFI-PE rotational line intensities due to near-resonance autoionization decreases as upsilon(+) increases. Experimental rotational constants for H-2(+) (X-2 Sigma(g)(+), upsilon(+) = 0,2,9 and 11) are determined with higher accuracy than those obtained in previous HeI and NeI photoelectron studies. In agreement with previous experimental and theoretical investigations, only the Delta N=0 and +/-2 rotational branches are observed in the PFI-PE spectrum for H-2. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：507 / 515

页数：9

共 38 条

[11] QUANTUM DEFECT ANALYSIS OF HD-PHOTOIONIZATION [J].