Quantum dots coordinated with conjugated organic ligands: new nanomaterials with novel photophysics

被引:54
作者
Hammer, Nathan I. [1 ]
Emrick, Todd [2 ]
Barnes, Michael D. [1 ]
机构
[1] Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA
[2] Univ Massachusetts, Dept Polymer Sci & Engn, Amherst, MA 01003 USA
来源
NANOSCALE RESEARCH LETTERS | 2007年 / 2卷 / 06期
基金
美国国家科学基金会;
关键词
single molecule spectroscopy; hybrid nanomaterial; quantum dot; blinking; conjugated polymer; energy transfer; charge transfer; photovoltaic; atomic force microscope;
D O I
10.1007/s11671-007-9062-8
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
CdSe quantum dots functionalized with oligo-(phenylene vinylene) (OPV) ligands (CdSe-OPV nanostructures) represent a new class of composite nanomaterials with significantly modified photophysics relative to bulk blends or isolated components. Single-molecule spectroscopy on these species have revealed novel photophysics such as enhanced energy transfer, spectral stability, and strongly modified excited state lifetimes and blinking statistics. Here, we review the role of ligands in quantum dot applications and summarize some of our recent efforts probing energy and charge transfer in hybrid CdSe-OPV composite nanostructures.
引用
收藏
页码:282 / 290
页数:9
相关论文
共 89 条
[11]   Quantum dot-based multiplexed fluorescence resonance energy transfer [J].
Clapp, AR ;
Medintz, IL ;
Uyeda, HT ;
Fisher, BR ;
Goldman, ER ;
Bawendi, MG ;
Mattoussi, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (51) :18212-18221
[12]   Can luminescent quantum dots be efficient energy acceptors with organic dye donors? [J].
Clapp, AR ;
Medintz, IL ;
Fisher, BR ;
Anderson, GP ;
Mattoussi, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (04) :1242-1250
[13]   Photophysics of dopamine-modified quantumdots and effects on biological systems [J].
Clarke, SJ ;
Hollmann, CA ;
Zhang, ZJ ;
Suffern, D ;
Bradforth, SE ;
Dimitrijevic, NM ;
Minarik, WG ;
Nadeau, JL .
NATURE MATERIALS, 2006, 5 (05) :409-417
[14]   Electroluminescence from single monolayers of nanocrystals in molecular organic devices [J].
Coe, S ;
Woo, WK ;
Bawendi, M ;
Bulovic, V .
NATURE, 2002, 420 (6917) :800-803
[15]  
COLVIN VL, 1994, NATURE, V370, P354, DOI 10.1038/370354a0
[16]   ELECTROLUMINESCENCE FROM CDSE QUANTUM-DOT POLYMER COMPOSITES [J].
DABBOUSI, BO ;
BAWENDI, MG ;
ONITSUKA, O ;
RUBNER, MF .
APPLIED PHYSICS LETTERS, 1995, 66 (11) :1316-1318
[17]   Diffusion dynamics of glycine receptors revealed by single-quantum dot tracking [J].
Dahan, M ;
Lévi, S ;
Luccardini, C ;
Rostaing, P ;
Riveau, B ;
Triller, A .
SCIENCE, 2003, 302 (5644) :442-445
[18]   In vivo imaging of quantum dots encapsulated in phospholipid micelles [J].
Dubertret, B ;
Skourides, P ;
Norris, DJ ;
Noireaux, V ;
Brivanlou, AH ;
Libchaber, A .
SCIENCE, 2002, 298 (5599) :1759-1762
[19]   Random telegraph signal in the photoluminescence intensity of a single quantum dot [J].
Efros, AL ;
Rosen, M .
PHYSICAL REVIEW LETTERS, 1997, 78 (06) :1110-1113
[20]   Color-selective semiconductor nanocrystal laser [J].
Eisler, HJ ;
Sundar, VC ;
Bawendi, MG ;
Walsh, M ;
Smith, HI ;
Klimov, V .
APPLIED PHYSICS LETTERS, 2002, 80 (24) :4614-4616