Tracking reactive intermediates in phosphine-promoted reactions with ambiphilic phosphino-boranes

被引：94

作者：

Moebs-Sanchez, Sylvie ^{[1
]}

Bouhadir, Ghenwa ^{[1
]}

Saffon, Nathalie ^{[3
]}

Maron, Laurent ^{[2
]}

Bourissou, Didier ^{[1
]}

机构：

[1] Univ Toulouse 3, Lab Heterochim Fdn & Appl, CNRS,UMR 5069, Equipe Ligands Bifonctionnels & Polymeres Biodegr, F-31062 Toulouse 9, France

[2] Univ Toulouse 3, INSA, Lab Phys & Chim Nanoobjets, UMR 5215, F-31077 Toulouse, France

[3] Univ Toulouse 3, FR 2599, F-31062 Toulouse 9, France

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 29期

关键词：

D O I：

10.1039/b805161e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ambiphilic phosphino-borane i-Pr2P(o-C6H4)BMes(2) affords stable versions of key zwitterionic intermediates by reactions with diethyl azodicarboxylate or PhNCO.

引用

页码：3435 / 3437

页数：3

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