(η6-arylhimachalene)tricarbonylchromium(0)

被引：6

作者：

Abouhamza, B ^{[1
]}

El Firdoussi, L

Allaoud, S

Karim, A

Barrero, AF

Quirós, M

机构：

[1] Fac Sci Semlalia, Chim Coordinat Lab, Marrakech, Morocco

[2] Univ Granada, Fac Ciencias, Dept Quim Organ, E-18071 Granada, Spain

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270198012876

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of Cr(CO)(6) with arylhimachalene yields the title aryl organometallic compound, tricarbonyl[(1,2,3,4,4a,9a-eta)-(7S)-3,5,5,9-tetramethyl-6,7,8,9-tetrahydro-5H-benzocycloheptene]chromium(0), [Cr(C15H22)(CO)(3)], with the hydrocarbon linked to a Cr(CO)(3) tripod group. The crystal structure of one of the stereoisomeric products, i.e. that with the tripod anti to the methyl group on the asymmetric carbon, is presented here.

引用

页码：361 / 363

页数：3

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