Alkali-metal-mediated coupling of a phosphorus-substituted alkene. Structural characterization of dilithium 1,1,4,4-tetrakis(diphenylphosphino)butane-1,4-diide

被引：20

作者：

Clegg, W ^{[1
]}

Izod, K ^{[1
]}

McFarlane, W ^{[1
]}

O'Shaughnessy, P ^{[1
]}

机构：

[1] Univ Newcastle Upon Tyne, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 24期

关键词：

D O I：

10.1021/om980741x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The butane-1,4-diide salt {(THF)(2)Li(Ph2P)(2)CCH2}(2) is obtained by treatment of(Ph2P)(2)C=CH2 with lithium in THF; hydrolysis of this salt yields the novel tetraphosphine {(Ph2P)(2)CHCH2}(2).

引用

页码：5231 / 5232

页数：2

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