A novel, internally-solvated phosphinomethanide;: crystal structure of Li[C(SiMe3)2{P(C6H4CH2NMe2-2)2}]

被引：17

作者：

Clegg, W ^{[1
]}

Doherty, S ^{[1
]}

Izod, K ^{[1
]}

O'Shaughnessy, P ^{[1
]}

机构：

[1] Univ Newcastle Upon Tyne, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 10期

关键词：

D O I：

10.1039/a801342j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metallation of P{CH(SiMe3)(2)}(C6H4CH2NMe2-2)(2) with (BuLi)-Li-n yields a novel lithium phosphinomethanide in which the ligand exhibits an unprecedented tridentate PN2 coordination mode and in which there are no short contacts between lithium and the planar carbanion centre.

引用

页码：1129 / 1130

页数：2

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