Catalytic C-H Bond Activation at Nanoscale Lewis Acidic Aluminium Fluorides: H/D Exchange Reactions at Aromatic and Aliphatic Hydrocarbons

被引：41

作者：

Prechtl, Martin H. G. ^{[1
]}

Teltewskoi, Michael ^{[1
]}

Dimitrov, Anton ^{[1
]}

Kemnitz, Erhard ^{[1
]}

Braun, Thomas ^{[1
]}

机构：

[1] Univ Berlin, Dept Chem, D-12489 Berlin, Germany

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2011年 / 17卷 / 51期

关键词：

aluminium fluorides; bifunctional catalysts; C-H activation; H/D exchange; Lewis acids; HYDROGEN-DEUTERIUM EXCHANGE; SOLID ACIDS; IONIC LIQUIDS; GAMMA-ALUMINA; RHODIUM; COMPLEXES; ALKANE; MILD; PALLADIUM; CHEMISTRY;

D O I：

10.1002/chem.201102853

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nanoscopic amorphous Lewis acidic aluminium fluorides, such as aluminium chlorofluoride (ACF) and high-surface aluminium fluoride (HS-AlF 3), are capable of activating C-H bonds of aliphatic hydrocarbons. H/D exchange reactions are catalysed under mild conditions (40 °C). © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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页码：14385 / 14388

页数：4

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