Crystallographic characterisation of binary alkali metal alkoxide magnesium bis(alkyl) mixtures:: differential binding of Na+ and K+ to a common dinuclear diorganomagnesiate

被引：26

作者：

Barnett, NDR

Clegg, W

Kennedy, AR

Mulvey, RE ^{[1
]}

Weatherstone, S

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

[2] Univ Newcastle Upon Tyne, Sch Nat Sci Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 03期

关键词：

D O I：

10.1039/b413191f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Relevant to mixtures studied in solution and utilised in styrene polymerisation but hitherto not characterised in the solid, two crystal structures of alkali metal alkoxide-magnesium bis(alkyl) co-complexes have been determined, revealing that in binding to the C2O tripodal face of a common organomagnesiate anion, Na+ prefers O-coordination, whereas K+ prefers C-coordination.

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收藏

页码：375 / 377

页数：3

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