Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates

被引：81

作者：

He, XY

Noll, BC

Beatty, A

Mulvey, RE

Henderson, KW

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

[2] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 24期

关键词：

D O I：

10.1021/ja048750m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Potassium, calcium, and mixed potassium-calcium amide combinations have been shown to be efficient reagents in enolization reactions, and a set of representative intermediate mono- and heterobimetallic enolates have been successfully isolated and crystallographically characterized. Copyright © 2004 American Chemical Society.

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页码：7444 / 7445

页数：2

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