Synthesis and structural characterisation of a magnesium bisenolate:: a tetrameric (Mg2O2)2 chain terminated by solvating ketone

被引：18

作者：

Allan, JF

Henderson, KW

Kennedy, AR

Teat, SJ

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

[2] SERC, Daresbury Lab, CCLRC, Warrington WA4 4AD, Cheshire, England

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 12期

关键词：

D O I：

10.1039/b002892o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A reactive magnesium enolate intermediate has been identified containing the remarkable composition of four metals, eight enolates (six bridging and two terminally bound) and two unenolised ketones, and its implications in the aldol addition reaction are discussed.

引用

页码：1059 / 1060

页数：2

共 15 条

[1]

ALLAN JE, UNPUB

[2] Bis(amido)magnesium mediated aldol additions: first structural characterisation of an amidomagnesium aldolate intermediate [J].