Organic Radical Battery Approaching Practical Use

被引：232

作者：

Nakahara, Kentaro ^{[1
,2
]}

Oyaizu, Kenichi ^{[1
]}

Nishide, Hiroyuki ^{[1
]}

机构：

[1] Waseda Univ, Dept Appl Chem, Shinjuku Ku, Tokyo 1698555, Japan

[2] NEC Corp Ltd, Green Innovat Res Labs, Tsukuba, Ibaraki 3508501, Japan

来源：

CHEMISTRY LETTERS | 2011年 / 40卷 / 03期

关键词：

ELECTRODE-ACTIVE MATERIAL; RECHARGEABLE LITHIUM BATTERIES; CHARGE/DISCHARGE PROPERTIES; ELECTROCHEMICAL PROPERTIES; POLYMER ELECTRODES; CATHODE MATERIAL; TEMPO; DEVICE; POLYNORBORNENE; POLYACETYLENE;

D O I：

10.1246/cl.2011.222

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrochemical redox reactions of organic polymers bearing robust unpaired electrons were investigated to determine the applicability of these polymers to rechargeable batteries. Such an "organic radical battery" would be environmentally friendly and have high-power characteristics. This highlight review describes the performance of a battery using a nitroxyl radical polymer as the cathode active material. The electron-transfer mechanism and recent developments that should lead to the practical application of the organic radical battery are also described.

引用

页码：222 / 227

页数：6

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