β-amino tertiary cycloalkanols for the enantioselective protonation of enolic species produced by a palladium-induced cascade reaction

被引：39

作者：

Aboulhoda, SJ

Reiners, I

Wilken, J

Hénin, F

Martens, J

Muzart, J

机构：

[1] Univ Reims Champagne Ardenne, CNRS, Unite Mixte Rech React Select & Appl, F-51687 Reims 2, France

[2] Univ Oldenburg, Fachbereich Chem, D-26129 Oldenburg, Germany

来源：

TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 11期

关键词：

D O I：

10.1016/S0957-4166(98)00189-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The palladium-induced cleavage of beta-ketoesters and enol carbonates derived from alpha-alkylated 1-indanones and 1-tetralones in the presence of substoichiometric amounts of various (S)-aminocycloalkanols led to optically active (R)-alpha-alkylated indanones and tetralones with enantiomeric excesses of up to 72%. (C) 1998 Elsevier Science Ltd, All rights reserved.

引用

页码：1847 / 1850

页数：4

共 22 条

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