Facile Catalytic Hydrosilylation of Pyridines

被引：140

作者：

Gutsulyak, Dmitry V. ^{[1
]}

van der Est, Art ^{[1
]}

Nikonov, Georgii I. ^{[1
]}

机构：

[1] Brock Univ, Dept Chem, 500 Glenridge Ave, St Catharines, ON L2S 3A1, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 06期

基金：

加拿大自然科学与工程研究理事会;

关键词：

chemoselectivity; heterocycles; hydrosilylation; ruthenium; zinc; ONE-POT CONVERSION; IRON-SILICON BOND; ASYMMETRIC HYDROSILYLATION; TRANSFER HYDROGENATION; ENANTIOSELECTIVE HYDROSILYLATION; TERTIARY-AMINES; NITRO-COMPOUNDS; REDUCTION; IMINES; AMIDES;

D O I：

10.1002/anie.201006135

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Not only surprisingly facile, a hydrosilylation of pyridines under the catalysis of [Cp(iPr3P)Ru(NCCH3)2]+ has the advantages that it is 1,4-regioselective and reversible. The products can be transformed in a variety of ways (see scheme). The related complex [CpRu(NCCH3)3]+ catalyzes the two-hydrogen-atom reduction of phenanthroline by HSiMe2Ph/water. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1384 / 1387

页数：4

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