Asymmetric synthesis using suffinimines (N-sulfinyl imines)

被引：12

作者：

Davis, FA ^{[1
]}

Yang, B ^{[1
]}

Deng, JH ^{[1
]}

Wu, YZ ^{[1
]}

Zhang, Y ^{[1
]}

Rao, A ^{[1
]}

Fang, TN ^{[1
]}

Goswami, R ^{[1
]}

Prasad, KR ^{[1
]}

Nolt, MB ^{[1
]}

Anilkumar, G ^{[1
]}

机构：

[1] Temple Univ, Dept Chem, Philadelphia, PA 19122 USA

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2005年 / 180卷 / 5-6期

关键词：

alkaloids; amines; asymmetric syuthesis; N-sulfinylimines; piperidine; pyrrolidine;

D O I：

10.1080/10426500590910648

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Sulfinimine-derived polyfunctionalized chiral building blocks, often prepared in one pot, provide efficient access, with a minimum of chemical manipulation, to enantiopure, multifunctional amine derivatives including piperdines and pyrrolidines.

引用

页码：1109 / 1117

页数：9

共 12 条

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ORGANIC LETTERS, 2004, 6 (08) :1269-1272

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[5] Asymmetric synthesis of the quinolizidine alkaloid (-)-epimyrtine with intramolecular Mannich Cyclization and n-sulfinyl δ-amino β-ketoesters [J].

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JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (21) :8061-8064

[6] N-sulfinyl β-amino Weinreb amides:: Synthesis of enantiopure β-amino carbonyl compounds.: Asymmetric synthesis of (+)-sedridine and (-)-allosedridine [J].

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ORGANIC LETTERS, 2002, 4 (04) :655-658

[8] Aziridine mediated asymmetric synthesis of α-benzylserine and α-n-butylserine [J].

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Zhang, ZJ .

TETRAHEDRON, 2001, 57 (30) :6345-6352

[9]

Davis FA, 1998, CHEM SOC REV, V27, P13

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Ellman, JA ;

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ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (11) :984-995

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