Immobilization of lithium-selective 14-crown-4 on crosslinked polymer supports

被引：28

作者：

Alexandratos, SD

Stine, CL

Sachleben, RA

Moyer, BA

机构：

[1] CUNY Hunter Coll, Dept Chem, New York, NY 10021 USA

[2] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

[3] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA

来源：

POLYMER | 2005年 / 46卷 / 17期

关键词：

polymer-supported reagent; ion; selective;

D O I：

10.1016/j.polymer.2004.10.091

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The immobilization of octamethyl-14-crown-4 onto crosslinked polymer supports is reported and the selectivity for Li(I) from aqueous solutions quantified. The amount of Li(I) complexed by the crown ether is affected by the polarity of the polymer matrix: Complexation increases with increasing matrix hydrophilicity. Poly(glycidyl methacrylate) is the preferred support matrix for the crown ether. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：6347 / 6352

页数：6

共 37 条

[21] PHASE-TRANSFER CATALYTIC ACTIVITY OF POLYMER-SUPPORTED MACROCYCLIC POLYETHERS [J].