Double click reaction strategies for polymer conjugation and post-functionalization of polymers

被引：177

作者：

Durmaz, Hakan ^{[2
]}

Sanyal, Amitav ^{[1
]}

Hizal, Gurkan ^{[2
]}

Tunca, Umit ^{[2
]}

机构：

[1] Bogazici Univ, Dept Chem, TR-34342 Istanbul, Turkey

[2] Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey

来源：

POLYMER CHEMISTRY | 2012年 / 3卷 / 04期

关键词：

ONE-POT SYNTHESIS; LIVING RADICAL POLYMERIZATION; FRAGMENTATION CHAIN TRANSFER; STAR-BLOCK-COPOLYMERS; DIELS-ALDER REACTION; THIOL-ENE CLICK; MACROMOLECULAR ARCHITECTURES; HETEROGRAFT COPOLYMERS; TRIBLOCK COPOLYMERS; FACILE SYNTHESIS;

D O I：

10.1039/c1py00471a

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Double click reaction strategies, which are a combination of different type of click reactions, allow the preparation of polymers with various topologies and the post-functionalization of polymers, which cannot be easily achieved by using only one click reaction. The most studied click reaction combinations may be listed as the Cu(I) catalyzed azide-alkyne cycloaddition (CuAAC)-Diels-Alder, and the CuAAC-nitroxide radical coupling reactions for polymer-polymer conjugation and the CuAAC-Diels-Alder, or the CuAAC-thiol-ene reactions for post-modification of polymers.

引用

页码：825 / 835

页数：11

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