Artificial photosynthetic systems. Using light and water to provide electrons and protons for the synthesis of a fuel

被引：95

作者：

Herrero, Christian ^{[1
]}

Quaranta, Annamaria ^{[1
]}

Leibl, Winfried ^{[1
]}

Rutherford, A. William ^{[1
]}

Aukauloo, Ally ^{[1
,2
]}

机构：

[1] CEA, iBiTec S, Serv Bioenerget Biol Struct & Mecanismes SB2SM, F-91191 Gif Sur Yvette, France

[2] Univ Paris 11, CNRS, Inst Chim Mol & Mat Orsay, UMR 8182, F-91405 Orsay, France

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2011年 / 4卷 / 07期

关键词：

O BOND FORMATION; OXYGEN-EVOLVING COMPLEX; PHOTOSYSTEM-II; RUTHENIUM(II) COMPLEXES; O-2-EVOLVING COMPLEX; MOLECULAR CATALYSTS; MANGANESE COMPLEXES; HYDROXYL RADICALS; REDOX PROPERTIES; O-2; EVOLUTION;

D O I：

10.1039/c0ee00645a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review covers the progress achieved in the synthesis and characterization of different metal based catalysts designed for the photocatalytic oxidation of water with special focus on molecular designed systems. In those cases where the mechanism of the light-driven catalytic activity of these complexes is not known, we have looked to published mechanisms related to chemically activated catalysts. We also discuss the choice of the chromophores used to sensitize these reactions as well as the recovery of the reaction products and nature of the electron acceptors used.

引用

页码：2353 / 2365

页数：13

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