Reactivity modulation in container molecules

被引：198

作者：

Breiner, Boris ^{[1
]}

Clegg, Jack K. ^{[1
]}

Nitschke, Jonathan R. ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

CHEMICAL SCIENCE | 2011年 / 2卷 / 01期

关键词：

SELF-ASSEMBLED CAPSULES; HOST-GUEST CHEMISTRY; SUPRAMOLECULAR CHEMISTRY; SYSTEMS CHEMISTRY; CARBOXYLIC-ACIDS; SPIN-CROSSOVER; DIELS-ALDER; CATALYSIS; ENCAPSULATION; RECEPTOR;

D O I：

10.1039/c0sc00329h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The encapsulation of a guest within a host molecule can open new pathways of guest reactivity or halt modes of reaction normally observed in solution. Recent findings illustrate how a host's size and shape may alter the regioselectivity and kinetics of guests' reactions within host molecules.

引用

页码：51 / 56

页数：6

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