Reactivity modulation in container molecules

被引：198

作者：

Breiner, Boris ^{[1
]}

Clegg, Jack K. ^{[1
]}

Nitschke, Jonathan R. ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

CHEMICAL SCIENCE | 2011年 / 2卷 / 01期

关键词：

SELF-ASSEMBLED CAPSULES; HOST-GUEST CHEMISTRY; SUPRAMOLECULAR CHEMISTRY; SYSTEMS CHEMISTRY; CARBOXYLIC-ACIDS; SPIN-CROSSOVER; DIELS-ALDER; CATALYSIS; ENCAPSULATION; RECEPTOR;

D O I：

10.1039/c0sc00329h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The encapsulation of a guest within a host molecule can open new pathways of guest reactivity or halt modes of reaction normally observed in solution. Recent findings illustrate how a host's size and shape may alter the regioselectivity and kinetics of guests' reactions within host molecules.

引用

页码：51 / 56

页数：6

共 67 条

[61] Reticular chemistry of metal-organic polyhedra [J].

Tranchemontagne, David J. L. ;

Ni, Zheng ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (28) :5136-5147

[62] Polynuclear coordination cages [J].

Ward, Michael D. .

CHEMICAL COMMUNICATIONS, 2009, (30) :4487-4499

[63] o-benzyne: Strained alkyne or cumulene? NMR characterization in a molecular container [J].

Warmuth, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (12) :1347-1350

[64] Highly Selective Monomethylation of Primary Amines Through Host-Guest Product Sequestration [J].

Yebeutchou, Roger M. ;

Dalcanale, Enrico .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (07) :2452-+

[65] Ship-in-a-bottle synthesis of otherwise labile cyclic trimers of siloxanes in a self-assembled coordination cage [J].

Yoshizawa, M ;

Kusukawa, T ;

Fujita, M ;

Yamaguchi, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (26) :6311-6312

[66] Diels-alder in aqueous molecular hosts: Unusual regioselectivity and efficient catalysis [J].

Yoshizawa, M ;

Tamura, M ;

Fujita, M .

SCIENCE, 2006, 312 (5771) :251-254

[67] Functional Molecular Flasks: New Properties and Reactions within Discrete, Self-Assembled Hosts [J].

Yoshizawa, Michito ;

Klosterman, Jeremy K. ;

Fujita, Makoto .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (19) :3418-3438

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