Silica sol-gel monolithic materials and their use in a variety of applications

被引:95
作者
Kato, M
Sakai-Kato, K
Toyo'oka, T
机构
[1] Univ Shizuoka, Sch Pharmaceut Sci, Dept Analyt Chem, Shizuoka 4228526, Japan
[2] Univ Shizuoka, COE Program 21st Century, Shizuoka 4228526, Japan
[3] Musashino Univ, Res Inst Pharmaceut Sci, Tokyo, Japan
关键词
silica sol-gel; analytical chemistry; biomolecule; monolith; high-througput screening;
D O I
10.1002/jssc.200500225
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Sol-gel technology was first discovered in the late 1800s, but it was not until the early 1970s that renewed interest in the technique was generated, when monolithic inorganic gels were formed at low temperature. In this review, we introduce the sol-gel reaction and the properties of the gel matrix in the first half and the applications of the matrix in the latter half.
引用
收藏
页码:1893 / 1908
页数:16
相关论文
共 146 条
[11]   Encapsulation of functional cells by sol-gel silica: actual progress and perspectives for cell therapy [J].
Carturan, G ;
Dal Toso, R ;
Boninsegna, S ;
Dal Monte, R .
JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (14) :2087-2098
[12]   High-performance liquid chromatographic enantioseparations on capillary columns containing monolithic [J].
Chankvetadze, B ;
Yamamoto, C ;
Tanaka, N ;
Nakanishi, K ;
Okamoto, Y .
JOURNAL OF SEPARATION SCIENCE, 2004, 27 (10-11) :905-911
[13]   Very fast enantioseparation in high-performance liquid chromatography using cellulose tris(3,5-dimethylphenylcarbamate) coated on monolithic silica support [J].
Chankvetadze, B ;
Yamamoto, C ;
Okamoto, Y .
CHEMISTRY LETTERS, 2003, 32 (09) :850-851
[14]   The use of 3 and 12 micron particulate stationary phases in voltage-assisted micro-LC for the separation of mixtures containing neutral, basic and acidic analytes [J].
Channer, B ;
Uhl, PU ;
Euerby, MR ;
McKeown, AP ;
Skellern, GG ;
Watson, DG .
CHROMATOGRAPHIA, 2005, 61 (3-4) :113-119
[15]   Practical evaluation of sol-gel and hydrothermal fritting technologies for rapid column fabrication and its application in capillary electrochromatography and micro-liquid chromatography [J].
Channer, B ;
Uhl, PU ;
Euerby, MR ;
McKeown, AP ;
Lomax, H ;
Skellern, GG ;
Watson, DG .
CHROMATOGRAPHIA, 2003, 58 (3-4) :135-143
[16]   Macroporous photopolymer frits for capillary electrochromatography [J].
Chen, JR ;
Dulay, MT ;
Zare, RN ;
Svec, F ;
Peters, E .
ANALYTICAL CHEMISTRY, 2000, 72 (06) :1224-1227
[17]   Electrochromatographic enantioseparation using chiral ligand exchange monolithic sol-gel column [J].
Chen, Z ;
Nishiyama, T ;
Uchiyama, K ;
Hobo, T .
ANALYTICA CHIMICA ACTA, 2004, 501 (01) :17-23
[18]   On-line monolithic enzyme reactor fabricated by sol-gel process for elimination of ascorbic acid while monitoring dopamine [J].
Chen, ZL ;
Hayashi, K ;
Iwasaki, Y ;
Kurita, R ;
Niwa, O ;
Sunaawa, K .
ELECTROANALYSIS, 2005, 17 (03) :231-238
[19]   Cyclodextrin-modified monolithic columns for resolving dansyl amino acid enantiomers and positional isomers by capillary electrochromatography [J].
Chen, ZL ;
Ozawa, H ;
Uchiyama, K ;
Hobo, T .
ELECTROPHORESIS, 2003, 24 (15) :2550-2558
[20]   Chemically modified chiral monolithic silica column prepared by a sol-gel process for enantiomeric separation by micro high-performance liquid chromatography [J].
Chen, ZL ;
Uchiyama, K ;
Hobo, T .
JOURNAL OF CHROMATOGRAPHY A, 2002, 942 (1-2) :83-91