Chemical dependence of interatomic X-ray transition energies and intensities -: a study of Mn Kβ" and Kβ2,5 spectra

被引：154

作者：

Bergmann, U

Horne, CR

Collins, TJ

Workman, JM

Cramer, SP ^{[1
]}

机构：

[1] Univ Calif Berkeley, Lawrence Berkeley Lab, Phys Biosci Div, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Environm Energy Technol Div, Berkeley, CA 94720 USA

[3] Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA

[4] Univ Calif Davis, Dept Appl Sci, Davis, CA 95616 USA

来源：

CHEMICAL PHYSICS LETTERS | 1999年 / 302卷 / 1-2期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0009-2614(99)00095-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A study of ligand (N, O, F) 2s to metal (Mn) 1s 'interatomic' or 'crossover' X-ray transitions is reported. We show that the energy of the K beta " feature is related to the ligand 2s binding energy and can be used to identify the type of ligand. For oxygen-ligated Mn compounds, the strength of the K beta " transition decreases exponentially with increasing Mn-O distance. This can be used to predict distances to similar to 0.1 Angstrom. The K beta(2,5) energy shows shifts of similar to 1 eV per unit oxidation state. K beta " and K beta(2,5) transitions are a promising tool for structural characterization of transition-metal complexes. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：119 / 124

页数：6

共 31 条

[11] SITE-SELECTIVE XANES AND EXAFS - A DEMONSTRATION WITH MANGANESE MIXTURES AND MIXED-VALENCE COMPLEXES
GRUSH, MM
CHRISTOU, G
HAMALAINEN, K
CRAMER, SP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (21) : 5895 - 5896
[12] ELECTRONIC-STRUCTURE OF LA2-XSRXCUO4 STUDIED BY RESONANT SOFT-X-RAY FLUORESCENCE SPECTROSCOPY
GUO, JH
WASSDAHL, N
SKYTT, P
BUTORIN, S
MA, Y
NORDGREN, J
[J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1993, 54 (10) : 1203 - 1206
[13] SPIN-POLARIZED PHOTOELECTRON DIFFRACTION AND VALENCE-BAND PHOTOEMISSION FROM MNO(001)
HERMSMEIER, B
OSTERWALDER, J
FRIEDMAN, DJ
SINKOVIC, B
TRAN, T
FADLEY, CS
[J]. PHYSICAL REVIEW B, 1990, 42 (18): : 11895 - 11913
[14] Resonant inelastic x-ray scattering in Nd2CuO4
Hill, JP
Kao, CC
Caliebe, WAL
Matsubara, M
Kotani, A
Peng, JL
Greene, RL
[J]. PHYSICAL REVIEW LETTERS, 1998, 80 (22) : 4967 - 4970
[15] METAL-LIGAND BONDING IN SOME VANADIUM COMPOUNDS - STUDY BASED ON X-RAY-EMISSION DATA
JONES, JB
URCH, DS
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (19): : 1885 - 1889
[16] X-ray resonant Raman scattering in NiO: Resonant enhancement of the charge-transfer excitations
Kao, CC
Caliebe, WAL
Hastings, JB
Gillet, JM
[J]. PHYSICAL REVIEW B, 1996, 54 (23): : 16361 - 16364
[17] Koningsberger D.C., 1988, X-Ray Absorption: Principles Applications, Techniques of EXAFS
[18] X-RAY K-BETA EMISSION SPECTRA AND ENERGY LEVELS OF COMPOUNDS OF 3D TRANSITION METALS .1. OXIDES
KOSTER, AS
MENDEL, H
[J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1970, 31 (11) : 2511 - &
[19] Theory of x-ray absorption and resonant x-ray emission spectra
Kotani, A
[J]. JOURNAL DE PHYSIQUE IV, 1997, 7 (C2): : 1 - 8
[20] ATOMIC RADIATIVE AND RADIATIONLESS YIELDS FOR K-SHELLS AND L-SHELLS
KRAUSE, MO
[J]. JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1979, 8 (02) : 307 - 327

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