meso-alkyl-substituted meso-meso linked diporphyrins and meso-alkyl-substituted meso-meso, β-β, β-β triply linked diporphyrins

被引：43

作者：

Hiroto, S

Osuka, A ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan

[2] Japan Sci & Technol Agcy, JST, CREST, Sakyo Ku, Kyoto 6068502, Japan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 70卷 / 10期

关键词：

D O I：

10.1021/jo0502192

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

AgPF6-promoted oxidation of 5,10,15-trialkyl zinc(II) porphyrins led to formation of meso-meso linked diporphyrins, which were further oxidized with Sc(OTf)(3) and DDQ to give meso-meso, beta-beta, beta-beta, triply linked diporphyrins that exhibited a stronger aggregation propensity than corresponding mesoaryl diporphyrins.

引用

页码：4054 / 4058

页数：5

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