Poly(ε-caprolactone) based nanocomposites reinforced by surface-grafted cellulose nanowhiskers via extrusion processing: Morphology, rheology, and thermo-mechanical properties

被引：150

作者：

Goffin, A. -L. ^{[1
]}

Raquez, J. -M. ^{[1
]}

Duquesne, E. ^{[1
]}

Siqueira, G. ^{[2
]}

Habibi, Y. ^{[1
,2
]}

Dufresne, A. ^{[2
]}

Dubois, Ph. ^{[1
]}

机构：

[1] Univ Mons, CIRMAP, Lab Polymer & Composite Mat, B-7000 Mons, Belgium

[2] Grenoble Inst Technol, Int Sch Paper Print Media & Biomat PAGORA, F-38402 St Martin Dheres, France

来源：

POLYMER | 2011年 / 52卷 / 07期

关键词：

Cellulose nanowhiskers; Poly(epsilon-caprolactone); Nanocomposites; ELASTIC-MODULUS; WHISKERS; NANOCRYSTALS; DISPERSION; BIOFIBRES; POLYMERS; FIBERS;

D O I：

10.1016/j.polymer.2011.02.004

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly((E)-epsilon caprolactone)-grafted cellulose nanowhiskers (extracted from ramie: CNWr) synthesized by ring-opening polymerization of the corresponding lactone [1] were studied as "masterbatches" by melt-blending within its commercial poly(epsilon-caprolactone) matrix (PCL). For sake of comparison, unmodified CNWr were also dispersed in PCL The goal of this study consists to evidence the impact of the covalent grafting of CNWr surface on thermo-mechanical properties of the commercial matrices. Atomic force microscopy (AFM) attests of the excellent dispersion of the cellulose nanowhiskers within PCL matrix. As a result of the excellent interfacial compatibility between the nanofiller and the matrix, the thermo-mechanical and theological performances were largely enhanced. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：1532 / 1538

页数：7

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