Gelation of helical polypeptide-random coil diblock copolymers by a nanoribbon mechanism

被引：90

作者：

Kim, KT

Park, C

Vandermeulen, GWM

Rider, DA

Kim, C

Winnik, MA

Manners, I

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

[2] Inha Univ, Dept Polymer Sci & Engn, Hyperstruct Organ Mat Res Ctr, Inchon 402751, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 48期

关键词：

block copolymers; organogels; polypepticles; self-assembly;

D O I：

10.1002/anie.200502809

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thermoreversible gelation of diblock copolymers of a helical polypeptide, poly(γ-benzyl-L-glutamate) and random-coil polymers such as polyferrocenylsilanes in dilute solution has been discovered (see picture). A new mechanism for self-assembly of block copolymers of helical polypeptides is proposed. (Figure Presented). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7964 / 7968

页数：5

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2-T