Thiols as interfacial modifiers to enhance the performance and stability of perovskite solar cells

被引:183
作者
Cao, Jing [1 ,2 ]
Yin, Jun [1 ,2 ,3 ]
Yuan, Shangfu [1 ,2 ]
Zhao, Yun [1 ,2 ]
Li, Jing [3 ]
Zheng, Nanfeng [1 ,2 ]
机构
[1] Xiamen Univ, Engn Res Ctr Nanopreparat Technol Fujian Prov, Collaborat Innovat Ctr Chem Energy Mat, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
[2] Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China
[3] Xiamen Univ, Pen Tung Sah Inst MicronanoSci & Technol, Xiamen 361005, Peoples R China
关键词
DYE;
D O I
10.1039/c5nr01820j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Modifying the interfaces of CH3NH3PbI3 with TiO2 and hole transport layers using two different types of thiols leads to enhanced performance and stability of perovskite solar cells. The incorporation of HOOC-Ph-SH at the TiO2/perovskite interface facilitates electron transfer from perovskite to TiO2 and also alters the morphology of perovskite crystal growth to increase the power conversion efficiency. The modification of pentafluorobenzenethiol at the perovskite/hole transport layer interface improves the stability.
引用
收藏
页码:9443 / 9447
页数:5
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