Application of time-resolved vibrational spectroscopy to the study of excited-state intercomponent processes in supramolecular systems

被引：14

作者：

Bignozzi, CA ^{[1
]}

Schoonover, JR ^{[1
]}

Dyer, RB ^{[1
]}

机构：

[1] LOS ALAMOS NATL LAB, BIOSCI & TECHNOL GRP, LOS ALAMOS, NM 87545 USA

来源：

COMMENTS ON INORGANIC CHEMISTRY | 1996年 / 18卷 / 02期

关键词：

supramolecular systems; polynuclear complexes; vibrational spectroscopy; excited states;

D O I：

10.1080/02603599608032715

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The application of time-resolved vibrational (Raman and infrared) spectroscopy to the study of excited-state intercomponent processes in inorganic chemistry represents a powerful new application of these techniques. The development of vibrational spectroscopy with time resolution from microseconds to femtoseconds to characterize the photochemistry and photophysics of metal-containing supramolecular systems provides a mechanism for understanding the fundamental processes which occur following photolysis. The utility and potential of this approach in the elucidation of excited-state processes is demonstrated with studies of excited-state localization, excited-state structure, and photoinduced intramolecular electron and energy transfer.

引用

页码：77 / 100

页数：24

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