Application of time-resolved vibrational spectroscopy to the study of excited-state intercomponent processes in supramolecular systems

被引：14

作者：

Bignozzi, CA ^{[1
]}

Schoonover, JR ^{[1
]}

Dyer, RB ^{[1
]}

机构：

[1] LOS ALAMOS NATL LAB, BIOSCI & TECHNOL GRP, LOS ALAMOS, NM 87545 USA

来源：

COMMENTS ON INORGANIC CHEMISTRY | 1996年 / 18卷 / 02期

关键词：

supramolecular systems; polynuclear complexes; vibrational spectroscopy; excited states;

D O I：

10.1080/02603599608032715

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The application of time-resolved vibrational (Raman and infrared) spectroscopy to the study of excited-state intercomponent processes in inorganic chemistry represents a powerful new application of these techniques. The development of vibrational spectroscopy with time resolution from microseconds to femtoseconds to characterize the photochemistry and photophysics of metal-containing supramolecular systems provides a mechanism for understanding the fundamental processes which occur following photolysis. The utility and potential of this approach in the elucidation of excited-state processes is demonstrated with studies of excited-state localization, excited-state structure, and photoinduced intramolecular electron and energy transfer.

引用

页码：77 / 100

页数：24

共 58 条

[51] TIME-RESOLVED INFRARED-SPECTROSCOPY OF EXCITED-STATES OF TRANSITION-METAL SPECIES [J].

TURNER, JJ ;

GEORGE, MW ;

JOHNSON, FPA ;

WESTWELL, JR .

COORDINATION CHEMISTRY REVIEWS, 1993, 125 (1-2) :101-114

[52] LIGAND-SPECIFIC CHARGE LOCALIZATION IN THE MLCT EXCITED-STATE OF RU(BPY)2(DPPHEN)2+ MONITORED BY TIME-RESOLVED RESONANCE RAMAN-SPECTROSCOPY [J].

TURRO, C ;

BOSSMANN, SH ;

LEROI, GE ;

BARTON, JK ;

TURRO, NJ .

INORGANIC CHEMISTRY, 1994, 33 (07) :1344-1347

[53] TIME-RESOLVED FT-IR ABSORPTION-SPECTROSCOPY USING A STEP-SCAN INTERFEROMETER [J].

UHMANN, W ;

BECKER, A ;

TARAN, C ;

SIEBERT, F .

APPLIED SPECTROSCOPY, 1991, 45 (03) :390-397

[54] TIME-RESOLVED STEP-SCAN FT-IR INVESTIGATIONS OF THE TRANSITION FROM KL TO L IN THE BACTERIORHODOPSIN PHOTOCYCLE - IDENTIFICATION OF CHROMOPHORE TWISTS BY ASSIGNING HYDROGEN-OUT-OF-PLANE (HOOP) BENDING VIBRATIONS [J].

WEIDLICH, O ;

SIEBERT, F .

APPLIED SPECTROSCOPY, 1993, 47 (09) :1394-1400

[55] MULTIPLE-STATE EMISSION AND INTRAMOLECULAR ELECTRON-TRANSFER QUENCHING IN RHENIUM(I) BIPYRIDINE BASED CHROMOPHORE QUENCHER COMPLEXES [J].

WESTMORELAND, TD ;

LEBOZEC, H ;

MURRAY, RW ;

MEYER, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (18) :5952-5954

[56]

Williams K. P. J., 1981, J CHEM SOC P2, V2, P852

[57] PICOSECOND DYNAMICS OF SOLVENT TRAPPING FOLLOWING ELECTRON-TRANSFER IN TRANSITION-METAL COMPLEXES [J].

YABE, T ;

ANDERSON, DR ;

ORMAN, LK ;

CHANG, YJ ;

HOPKINS, JB .

JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (06) :2302-2306

[58] PICOSECOND RAMAN INVESTIGATION OF INTERLIGAND ELECTRON-TRANSFER IN RUTHENIUM(II) COMPLEXES [J].

YABE, T ;

ORMAN, LK ;

ANDERSON, DR ;

YU, SC ;

XU, XB ;

HOPKINS, JB .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (18) :7128-7132

← 1 2 3 4 5 6 →