Ternary nets formed by self-assembly of triangles, squares, and tetrahedra

被引：176

作者：

Wang, ZQ ^{[1
]}

Kravtsov, VC ^{[1
]}

Zaworotko, MJ ^{[1
]}

机构：

[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 19期

关键词：

coordination polymers; crystal engineering; self-assembly; zinc;

D O I：

10.1002/anie.200500156

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Three not of a kind: Two metal-organic nets sustained by three different molecular building blocks, triangles, squares, and tetrahedra, are prepared and characterized. The shapes (see picture red triangles, green squares, yellow tetrahedra) reveal how appropriate combinations of vertex-linked polygons or polyhedra afford novel topologies that could be prototypal of an even wider range of organic and metal-organic compounds. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2877 / 2880

页数：4

共 84 条

[1]

Abrahams B. F., 2003, ANGEW CHEM, V115, P1144

[2] A Wellsian 'three-dimensional' racemate: Eight interpenetrating, enantiomorphic (10,3)-a nets, four right- and four left-handed [J].