Palladium-assisted intramolecular formation of N-heterocycles by sp(2) N nucleophilic attack on eta(3)-alkyl-Pd complexes generated by allene insertion into sigma Pd-C bond.

被引：16

作者：

Chengebroyen, J ^{[1
]}

Pfeffer, M ^{[1
]}

Sirlin, C ^{[1
]}

机构：

[1] UNIV STRASBOURG 1,CNRS,LAB SYNTH METALLOINDUITES,F-67070 STRASBOURG,FRANCE

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 40期

关键词：

D O I：

10.1016/0040-4039(96)01660-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,1-dimethylallene inserts into the sigma Pd-C bond of a series of cyclopalladated pyridine derivatives leading to stable or unstable eta(3)-allyl-Pd complexes. The demetallation of the latter leads to pyridinium derivatives with good yields. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：7263 / 7266

页数：4

共 29 条

[21] ANTI- AND SYN-ISOMERS OF A PI-ALLYLPALLADIUM CHLORIDE COMPLEX [J].

LUKAS, J ;

COREN, S ;

BLOM, JE .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1969, (22) :1303-&

[22] SELECTIVE HETERO-CYCLE AND CARBO-CYCLE SYNTHESES VIA MASKED CYCLOPALLADATED SECONDARY AMINE AND KETONE FUNCTIONS [J].

MAASSARANI, F ;

PFEFFER, M ;

SPENCER, J ;

WEHMAN, E .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 466 (1-2) :265-271

[23]

NAKAMURA J, 1977, CHEM ABSTR P195207D, V86

[24] SELECTED APPLICATIONS TO ORGANIC-SYNTHESIS OF INTRAMOLECULAR C-H ACTIVATION REACTIONS BY TRANSITION-METALS [J].

PFEFFER, M .

PURE AND APPLIED CHEMISTRY, 1992, 64 (03) :335-342

[25] FACILE SYNTHESIS OF HIGHLY SUBSTITUTED PD-ETA(3)-ALLYL COMPLEXES CONTAINING NITROGEN LIGANDS [J].

RULKE, RE ;

KLIPHUIS, D ;

ELSEVIER, CJ ;

FRAANJE, J ;

GOUBITZ, K ;

VANLEEUWEN, PWNM ;

VRIEZE, K .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (15) :1817-1819

[26] PHARMACOLOGICAL ACTIONS OF BERBERINE ON CENTRAL NERVOUS SYSTEM [J].

SHANBHAG, SM ;

KULKARNI, HJ ;

GAITONDE, BB .

JAPANESE JOURNAL OF PHARMACOLOGY, 1970, 20 (04) :482-&

[27] DISCOVERY OF 6,11-ETHANO-12,12-DIARYL-6,11-DIHYDROBENZO[B]QUINOLIZINIUM CATIONS, A NOVEL CLASS OF N-METHYL-D-ASPARTATE ANTAGONISTS [J].

SUBRAMANYAM, C ;

MALLAMO, JP ;

DORITY, JA ;

EARLEY, WG ;

KUMAR, V ;

AIMONE, LD ;

AULT, B ;

MILLER, MS ;

LUTTINGER, DA ;

DEHAVENHUDKINS, DL .

JOURNAL OF MEDICINAL CHEMISTRY, 1995, 38 (01) :21-27

[28] PALLADIUM-MEDIATED INTRAMOLECULAR C-N BOND FORMATION BETWEEN TERTIARY-AMINES AND ALKENES [J].

VANDERSCHAAF, PA ;

SUTTER, JP ;

GRELLIER, M ;

VANMIER, GPM ;

SPEK, AL ;

VANKOTEN, G ;

PFEFFER, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (12) :5134-5144

[29] NUCLEAR MAGNETIC RESONANCE STUDIES IN COORDINATION CHEMISTRY .4. REACTIONS OF PI-ALLYLPALLADIUM COMPLEXES AS INFLUENCED BY VARIOUS PHOSPHORUS LIGANDS [J].

VRIEZE, K ;

PRAAT, AP ;

COSSEE, P .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1968, 12 (03) :533-&

← 1 2 3 →