A novel, highly efficient and selective desilylating method for trialkylsilyl ethers

被引：43

作者：

Lee, ASY ^{[1
]}

Yeh, HC ^{[1
]}

Shie, JJ ^{[1
]}

机构：

[1] Tamkang Univ, Dept Chem, Tamsui 251, Taiwan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 29期

关键词：

D O I：

10.1016/S0040-4039(98)01035-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of tert-butyldimethylsilyl, tert-butyldiphenylsilyl and triisopropylsilyl ethers are hydrolyzed to theirs corresponding alcohols in CBr4/CH3OH (0.1 eq. / 10mL) reaction system under refluxing condition. The chemoselectivity can be achieved between primary and secondary triisopropylsilyl ethers when more hindered 2-propanol is used instead of methanol. (C) 1998 Elsevier Science Ltd. All rights reserved.

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页码：5249 / 5252

页数：4

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