Corundum, diamond, and PtS metal-organic frameworks with a difference:: self-assembly of a unique pair of 3-connecting D2d-symmetric 3,3′,5,5′-tetrakis(4-pyridyl)bimesityl

被引：161

作者：

Natarajan, R

Savitha, G

Dominiak, P

Wozniak, K

Moorthy, JN ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India

[2] Univ Warsaw, Dept Chem, PL-02093 Warsaw, Poland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 14期

关键词：

coordination modes; crystal engineering; N ligands; self-assembly; supramolecular chemistry;

D O I：

10.1002/anie.200461625

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) A ligand with a twist: The coordination of distorted-tetrahedral D2d-symmetric tetrapyridylbimesityl (tpb) with Oh, Td, and D4h metal centers leads to metal-organic frameworks with unprecedented topologies related to those of corundum, diamond, and PtS, respectively (see picture). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2115 / 2119

页数：5