1D-3D Metal-Organic Lattice Assemblies through Chemical Reactivity and Metal-Assisted Ligand Transformations in Ternary Pb(II)-Phenanthroline-(Hydroxy)dicarboxylic Acid Systems

被引：35

作者：

Gabriel, C. ^{[1
]}

Raptopoulou, C. P. ^{[2
]}

Psycharis, V. ^{[2
]}

Terzis, A. ^{[2
]}

Zervou, M. ^{[3
]}

Mateescu, C. ^{[4
]}

Salifoglou, A. ^{[1
]}

机构：

[1] Aristotle Univ Thessaloniki, Dept Chem Engn, Inorgan Chem Lab, Thessaloniki 54124, Greece

[2] NCSR Demokritos, Inst Mat Sci, Athens 15310, Greece

[3] Natl Hellen Res Fdn, Lab Mol Anal, Inst Organ & Pharmaceut Chem, Athens 11635, Greece

[4] Banat Univ Agr Sci & Vet Med, Timisoara 1900, Romania

来源：

CRYSTAL GROWTH & DESIGN | 2011年 / 11卷 / 02期

关键词：

HUISGEN 1,3-DIPOLAR CYCLOADDITION; SECONDARY BUILDING UNITS; CLICK CHEMISTRY APPROACH; PI-PI STACKINGS; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; LONE-PAIR; N-OXIDE; LUMINESCENT PROPERTIES; 3-DIMENSIONAL NETWORK;

D O I：

10.1021/cg100907p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Variable-pH hydrothermal reactions of Pb(II) with dicarboxylic acids in the presence of 1,10-phenanthroline led to new solid-state compounds [Pb-2(C12H8N2)(4)(C4H2O4)[(NO3)(2) (1), [Pb-2(C12H8N2)(4)(CO3)(C4H2O4)](n)center dot 6nH(2)O (2), [Pb-2(C12H8N2)(C4H2O4)(2)](n), (3), and [Pb(C12H8N2)(C4H2O4)](n)center dot 2nH(2)O (4). All compounds were characterized by elemental analysis, FT-IR, CP-MAS NMR, and single crystal X-ray diffraction. The collective chemical reactivity in the ternary Pb(II)phenanthroline-dicarboxylate systems unravels seldom seen metal-assisted ligand malate/maleate to fumarate transformations, which in the presence of Pb(II) and 1,10-phenanthroline contribute to the assembly of 2D (2) and 3D lattice networks (3 and 4). All distinct assemblies in 1-4 reveal interwoven crystal lattice connections, reflecting unique physicochemical properties.

引用

页码：382 / 395

页数：14

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