1D-3D Metal-Organic Lattice Assemblies through Chemical Reactivity and Metal-Assisted Ligand Transformations in Ternary Pb(II)-Phenanthroline-(Hydroxy)dicarboxylic Acid Systems

被引：35

作者：

Gabriel, C. ^{[1
]}

Raptopoulou, C. P. ^{[2
]}

Psycharis, V. ^{[2
]}

Terzis, A. ^{[2
]}

Zervou, M. ^{[3
]}

Mateescu, C. ^{[4
]}

Salifoglou, A. ^{[1
]}

机构：

[1] Aristotle Univ Thessaloniki, Dept Chem Engn, Inorgan Chem Lab, Thessaloniki 54124, Greece

[2] NCSR Demokritos, Inst Mat Sci, Athens 15310, Greece

[3] Natl Hellen Res Fdn, Lab Mol Anal, Inst Organ & Pharmaceut Chem, Athens 11635, Greece

[4] Banat Univ Agr Sci & Vet Med, Timisoara 1900, Romania

来源：

CRYSTAL GROWTH & DESIGN | 2011年 / 11卷 / 02期

关键词：

HUISGEN 1,3-DIPOLAR CYCLOADDITION; SECONDARY BUILDING UNITS; CLICK CHEMISTRY APPROACH; PI-PI STACKINGS; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; LONE-PAIR; N-OXIDE; LUMINESCENT PROPERTIES; 3-DIMENSIONAL NETWORK;

D O I：

10.1021/cg100907p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Variable-pH hydrothermal reactions of Pb(II) with dicarboxylic acids in the presence of 1,10-phenanthroline led to new solid-state compounds [Pb-2(C12H8N2)(4)(C4H2O4)[(NO3)(2) (1), [Pb-2(C12H8N2)(4)(CO3)(C4H2O4)](n)center dot 6nH(2)O (2), [Pb-2(C12H8N2)(C4H2O4)(2)](n), (3), and [Pb(C12H8N2)(C4H2O4)](n)center dot 2nH(2)O (4). All compounds were characterized by elemental analysis, FT-IR, CP-MAS NMR, and single crystal X-ray diffraction. The collective chemical reactivity in the ternary Pb(II)phenanthroline-dicarboxylate systems unravels seldom seen metal-assisted ligand malate/maleate to fumarate transformations, which in the presence of Pb(II) and 1,10-phenanthroline contribute to the assembly of 2D (2) and 3D lattice networks (3 and 4). All distinct assemblies in 1-4 reveal interwoven crystal lattice connections, reflecting unique physicochemical properties.

引用

页码：382 / 395

页数：14

共 153 条

[131] Assembly of a three-dimensional polyknotted coordination polymer [J].

Withersby, MA ;

Blake, AJ ;

Champness, NR ;

Cooke, PA ;

Hubberstey, P ;

Schröder, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (17) :4044-4046

[132] Heterogeneous asymmetric catalysis with homochiral metal-organic frameworks: Network-structure-dependent catalytic activity [J].

Wu, Chuan-De ;

Lin, Wenbin .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (07) :1075-1078

[133] C5H5-bridged dimeric ruthenium complexes [J].

Xia, HP ;

Jia, GC .

ORGANOMETALLICS, 1997, 16 (01) :1-4

[134]

Xiong RG, 2002, ANGEW CHEM INT EDIT, V41, P3800, DOI 10.1002/1521-3773(20021018)41:20<3800::AID-ANIE3800>3.0.CO

[135]

2-3

[136] In situ ligand synthesis and the first crystallographically characterized lanthanide 3-D pillared networks containing benzene-1,4-disulfonate as a building block [J].

Xiong, RG ;

Zhang, J ;

Chen, ZF ;

You, XZ ;

Che, CM ;

Fun, HK .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (06) :780-782

[137] Reticular synthesis and the design of new materials [J].

Yaghi, OM ;

O'Keeffe, M ;

Ockwig, NW ;

Chae, HK ;

Eddaoudi, M ;

Kim, J .

NATURE, 2003, 423 (6941) :705-714

[138] Syntheses, characterizations and crystal structures of two lead(II) diphosphonates:: Pb2[NH(CH2PO3)2]•2H2O and Pb3[HO2C(CH2)3NH(CH2PO3)2]2•2H2O [J].

Yang, BP ;

Sun, ZM ;

Mao, JG .

INORGANICA CHIMICA ACTA, 2004, 357 (05) :1583-1588

[139] Organic-acid effect on the structures of a series of Lead(II) complexes [J].

Yang, Jin ;

Ma, Jian-Fang ;

Liu, Ying-Ying ;

Ma, Ji-Cheng ;

Batten, Stuart R. .

INORGANIC CHEMISTRY, 2007, 46 (16) :6542-6555

[140] Structural variation from 1D to 3D: Effects of ligands and solvents on the construction of lead(II)-organic coordination polymers [J].

Yang, Jin ;

Li, Guo-Dong ;

Cao, Jun-Jun ;

Yue, Qi ;

Li, Guang-Hua ;

Chen, Jie-Sheng .

CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (11) :3248-3261

← 7 8 9 10 11 12 13 14 15 16 →