Catalytic activities of a bis(carbene)-derived nickel(II)-pincer complex in Kumada-Tamao-Corriu and Suzuki-Miyaura coupling reactions for the synthesis of biaryl compounds

被引：66

作者：

Inamoto, Kiyofumi ^{[1
]}

Kuroda, Jun-ichi ^{[1
]}

Sakamoto, Takao ^{[1
]}

Hiroya, Kou ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Pharmaceut Sci, Sendai, Miyagi 980, Japan

来源：

SYNTHESIS-STUTTGART | 2007年 / 18期

关键词：

nickel; N-heterocyclic carbenes; pincer ligands; Kumada-Tamao-Corriu coupling; Suzuki-Miyaura coupling;

D O I：

10.1055/s-2007-983845

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The catalytic activities of a pincer type bis(imidazolin-2-ylidene)nickel(II) complex were evaluated. The complex was found to be an effective catalyst in the Kumada-Tamao-Corriu and Suzuki-Miyaura coupling reactions of a broad range of aryl-X (X = Br, Cl and F) compounds, providing a variety of biaryl compounds, generally in good yield.

引用

页码：2853 / 2861

页数：9

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