Tuning the Spin State of Cobalt in a Co-La Heterometallic Complex through Controllable Coordination Sphere of La

被引：51

作者：

Bao, Song-Song ^{[1
]}

Liao, Yi ^{[3
]}

Su, Yan-Hui ^{[1
]}

Liang, Xu ^{[1
]}

Hu, Feng-Chun ^{[2
]}

Sun, Zhihu ^{[2
]}

Zheng, Li-Min ^{[1
]}

Wei, Shiqiang ^{[2
]}

Alberto, Roger ^{[4
]}

Li, Yi-Zhi

Ma, Jing ^{[3
]}

机构：

[1] Nanjing Univ, Sch Chem & Chem Engn, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230029, Peoples R China

[3] Nanjing Univ, Sch Chem & Chem Engn, Theoret & Computat Chem Inst, Nanjing 210093, Peoples R China

[4] Univ Zurich, Inst Inorgan Chem, CH-8057 Zurich, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 24期

关键词：

cobalt; heterometallic complexes; lanthanum; magnetic properties; N; O ligands; PHOTOINDUCED VALENCE TAUTOMERISM; INDUCED ELECTRON-TRANSFER; PRUSSIAN BLUE ANALOGS; MAGNETIC BISTABILITY; LINKAGE ISOMERISM; METAL-COMPLEXES; TRANSITION; CYANIDE; CROSSOVER; LIGANDS;

D O I：

10.1002/anie.201007872

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Reversible dehydration of complex 1 switches the spin state of cobalt from low-spin (LS) CoIII to high-spin (HS) CoII (see picture) and allows the magnetic moment to be varied from 0.48I B at 120 °C to 4.15I B at 220 deg;C in fully dehydrated complex 1-220. notpH6=1,4,7-triazacyclononane-1,4,7-triyl-tris(methylenephosphonic acid). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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收藏

页码：5504 / 5508

页数：5

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