Modern amination reactions

被引：160

作者：

Kienle, Marcel ^{[1
]}

Dubbaka, Srinivas Reddy ^{[1
]}

Brade, Katia ^{[1
]}

Knochel, Paul ^{[1
]}

机构：

[1] Univ Munich, Dept Chem, D-81377 Munich, Germany

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 2007卷 / 25期

关键词：

Amines; C-N bond formation; electrophilic amination; oxidative couplings;

D O I：

10.1002/ejoc.200700391

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of functionalized aromatic and heteroaromatic amines has attracted much interest due to their importance as building blocks for pharmaceuticals, polymers, or materials. In this microreview, new developments involving palladium-, nickel-, and copper-catalyzed animation reactions are discussed. The synthesis of functionalized secondary amines or diarylamines by addition of polyfunctionalized arylmagnesium reagents to nitroarenes or arylazo tosylates is also presented. Finally, primary, secondary, and tertiary amines prepared by the oxidative coupling of polyfunctional lithium amidocuprates using chloranil as oxidant are highlighted. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).

引用

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页码：4166 / 4176

页数：11

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