Band gap narrowing and fluorescence properties of nickel doped SnO2 nanoparticles

被引:302
作者
Ahmed, Arham S. [1 ]
Muhamed, Shafeeq M. [1 ]
Singla, M. L. [3 ]
Tabassum, Sartaj [2 ]
Naqvi, Alim H. [1 ]
Azam, Ameer [1 ]
机构
[1] Aligarh Muslim Univ, Dept Appl Phys, ZH Coll Engn & Technol, Ctr Excellence Mat Sci Nanomat, Aligarh 202002, Uttar Pradesh, India
[2] Aligarh Muslim Univ, Dept Chem, Aligarh 202002, Uttar Pradesh, India
[3] CSIR, CSIO, Mat Res & Bio Nanotechnol Div, Chandigarh 160030, India
关键词
Tin oxide nanoparticles; Sol-gel; XRD; Band gap; Fluorescence; TIN OXIDE; LUMINESCENT PROPERTIES; OPTICAL-PROPERTIES; ENERGY-TRANSFER; PHOTOLUMINESCENCE; THIN; TRANSPARENT; OXIDATION; SURFACE; GROWTH;
D O I
10.1016/j.jlumin.2010.07.017
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Nickel-doped tin oxide nanoparticles (sub-5 nm size) with intense fluorescence emission behavior have been synthesized by sol-gel route The structural and compositional analysis has been carried out by using XRD TEM FESEM and EDAX The optical absorbance spectra indicate a band gap narrowing effect and it was found to increase with the increase in nickel concentration The band gap narrowing at low dopant concentration (< 5%) can be assigned to SnO2-SnO2-x,,, alloying effect and for higher doping it may be due to the formation of defect sub-bands below the conduction band (c) 2010 Elsevier B V All rights reserved
引用
收藏
页码:1 / 6
页数:6
相关论文
共 41 条
[1]   Study of low temperature elaborated tailored optical band gap β-In2S3-3xO3x thin films [J].
Barreau, N ;
Bernède, JC ;
Marsillac, S ;
Mokrani, A .
JOURNAL OF CRYSTAL GROWTH, 2002, 235 (1-4) :439-449
[2]   SAXS study of formation and growth of tin oxide nanoparticles in the presence of complexing ligands [J].
Broussous, L ;
Santilli, CV ;
Pulcinelli, SH ;
Craievich, AF .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (11) :2855-2860
[3]  
CASTILLO JD, 2005, NANOTECHNOLOGY, V16, pS300
[4]   TRANSPARENT CONDUCTORS - A STATUS REVIEW [J].
CHOPRA, KL ;
MAJOR, S ;
PANDYA, DK .
THIN SOLID FILMS, 1983, 102 (01) :1-46
[5]   Synthesis and characterization of crystalline tin oxide nanoparticles [J].
de Monredon, S ;
Cellot, A ;
Ribot, F ;
Sanchez, C ;
Armelao, L ;
Gueneau, L ;
Delattre, L .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (08) :2396-2400
[6]   Morphological analysis of nanocrystalline SnO2 for gas sensor applications [J].
Dieguez, A ;
RomanoRodriguez, A ;
Morante, JR ;
Weimar, U ;
SchweizerBerberich, M ;
Gopel, W .
SENSORS AND ACTUATORS B-CHEMICAL, 1996, 31 (1-2) :1-8
[7]   Enhanced photoluminescence of Tb3+ and Eu3+ induced by energy transfer from SnO2 and Si nanocrystallites [J].
Elhouichet, H ;
Othman, L ;
Moadhen, A ;
Ouestlati, M ;
Roger, JA .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2003, 105 (1-3) :8-11
[8]   Synthesis and characterization of mesoporous indium tin oxide possessing an electronically conductive framework [J].
Emons, TT ;
Li, JQ ;
Nazar, LF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (29) :8516-8517
[9]   Microstructure and luminescence properties of Co-doped SnO2 nanoparticles synthesized by hydrothermal method [J].
Fang, L. M. ;
Zu, X. T. ;
Li, Z. J. ;
Zhu, S. ;
Liu, C. M. ;
Wang, L. M. ;
Gao, F. .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2008, 19 (8-9) :868-874
[10]   Synthesis and characteristics of Fe3+-doped SnO2 nanoparticles via sol-gel-calcination or sol-gel-hydrothermal route [J].
Fang, L. M. ;
Zu, X. T. ;
Li, Z. J. ;
Zhu, S. ;
Liu, C. M. ;
Zhou, W. L. ;
Wang, L. M. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 454 (1-2) :261-267