Chemoenzymatic autocatalytic Baeyer-Villiger oxidation

被引：27

作者：

Pchelka, BK

Gelo-Pujic, M

Guibe-Jampel, E

机构：

[1] Univ Paris Sud, Inst Chim Mol Orsay, Lab React Select Supports, CNRS,URA 478, F-91405 Orsay, France

[2] Warsaw Univ Technol, Dept Chem, ZTiBSL, PL-00661 Warsaw, Poland

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1998年 / 17期

关键词：

D O I：

10.1039/a804426k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Autocatalytic Baeyer-Villiger oxidation of cyclic ketones to lactones mediated by lipases has been achieved under extremely mild conditions in dry media using urea-hydrogen peroxide as the primary oxidant. Lipase catalysed perhydrolysis is enantiospecific and gives 6-substituted caprolactones or the corresponding hydroxy acids in enantiomerically enriched form.

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页码：2625 / 2627

页数：3

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