Supramolecular chirogenesis in weakly interacting hosts: Role of the temperature, structural, and electronic factors in enhancement of chiroptical sensitivity

被引：14

作者：

Borovkov, Victor

Yamamoto, Takuro

Higuchi, Hiroyuki

Inoue, Yoshihisa

机构：

[1] Osaka Univ, Dept Appl Chem, Suita, Osaka 5650871, Japan

[2] Osaka Univ, Japan Sci & Technol Agcy, Suita, Osaka 5650871, Japan

[3] Toyama Univ, Fac Sci, Dept Chem, Toyama 9308555, Japan

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 06期

关键词：

D O I：

10.1021/ol800179c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new supramolecular chirogenic system on the basis of tetrakis(nickel porphyrin) and various enantiopure solvents, which was specifically designed for investigation of the chirogenic phenomenon upon extremely weak interaction modes and marginal chiroptical responses, is reported. The temperature was found to be a key factor controlling the chirality transfer process in these assemblies.

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页码：1283 / 1286

页数：4

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