Rhenium-templated regioselective polyhydrogenation reaction of [60]fullerene

被引：32

作者：

Toganoh, M ^{[1
]}

Matsuo, Y ^{[1
]}

Nakamura, E ^{[1
]}

机构：

[1] Univ Tokyo, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 30期

关键词：

cyclopentadienyl ligands; fullerenes; hydrogenation; hydrometallation; rhenium;

D O I：

10.1002/anie.200351722

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Functionalizing fullerenes: The first regioselective polyhydrogenation of [60]fullerene has been achieved. Upon treatment of [60]fullerene or its derivative with 9,10-dihydroanthracene in the presence of [Re 2(CO)10], transfer hydrometallation reaction takes place to give a polyhydrogenation product (see scheme). The reaction provided a pathway to a variety of metal η5 complexes of hydrofullerenes.

引用

页码：3530 / 3532

页数：3

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