Facile Synthesis of Vanadium Metal-Organic Frameworks and their Magnetic Properties

被引：49

作者：

Centrone, Andrea ^{[1
]}

Harada, Takuya ^{[1
]}

Speakman, Scott ^{[2
]}

Hatton, T. Alan ^{[1
]}

机构：

[1] MIT, Dept Chem Engn, Cambridge, MA 02139 USA

[2] MIT, Ctr Mat Sci & Engn, Cambridge, MA 02139 USA

来源：

SMALL | 2010年 / 6卷 / 15期

基金：

美国国家科学基金会;

关键词：

magnetic properties; metal-organic frameworks; micro-wave synthesis; SQUID; XPS; HIGH-CAPACITY; SELECTIVE ADSORPTION; MICROWAVE SYNTHESIS; CARBON-DIOXIDE; STORAGE; HYDROGEN; METHANE; MIL-47; SEPARATION; CHEMISTRY;

D O I：

10.1002/smll.201000773

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The facile microwave syntheses of MIL-47 and six new vanadium-metal- organic-framework (V-MOF) materials are described. Small changes in the material crystal structure or removal of guest molecules affects the interactions between the V ions and, consequently, the magnetic properties of the MOF (see image). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA Weinheim.

引用

页码：1598 / 1602

页数：5

共 36 条

[31] Exceptional H2 saturation uptake in microporous metal-organic frameworks [J].