Selective organic synthesis via group 6 metal carbene complexes

被引：50

作者：

Barluenga, J

机构：

[1] Inst. Univ. Quim. Orgmet. Enrique M., Universidad de Oviedo, 33071-Oviedo, C/ Julían Clavería

来源：

PURE AND APPLIED CHEMISTRY | 1996年 / 68卷 / 03期

关键词：

D O I：

10.1351/pac199668030543

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first examples of asymmetric Michael addition of lithium reagents to chiral vinylalkoxycarbene chromium complexes 2 is reported. The [4+3] annulation of azadienes and 2-aminodienes is accomplished with complexes 2. Vinylaminocarbenes cyclopropanate alkenes and dienes and allows to isolate two new intermediates in the Dotz reaction. Some features of the [4+2] cycloaddition of chiral 2-aminodienes with both s-cis and s-trans Fischer vinylcarbene complexes are also presented.

引用

页码：543 / 552

页数：10

共 28 条

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