Molecule-based ferroelectric thin films: Mononuclear lanthanide enantiomers displaying room-temperature ferroelectric and dielectric properties

被引：102

作者：

Li, Xi-Li

Chen, Kai

Liu, Yu

Wang, Zhao-Xi

Wang, Tian-Wei

Zuo, Jing-Lin

Li, Yi-Zhi

Wang, Yue

Zhu, Jin Song

Liu, Jun-Min

Song, You ^{[1
]}

You, Xiao-Zeng

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Nanjing Univ, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China

[3] Nanjing Univ, Dept Phys, Solid State Microstruct Lab, Nanjing 210093, Peoples R China

[4] Jilin Univ, Coll Chem, Minist Educ, Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 36期

关键词：

chirality; circular dichroism; ferroelectric materials; lanthanides; thin films;

D O I：

10.1002/anie.200701802

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Graph Presented) Eu-reka! Two neutral mononuclear europium enantiomers [Eu(tta)3L] and their thin films were prepared (tta = 2-thenoyltrifluoroacetonate; L = (-)-4,5-pinene bipyridine (1), L = (+)-4,5-pinene bipyridine (2)). The ferroelectric measurements of the thin films show E-P hysteresis loops at room temperature (Tc = 28.0°C) with remnant polarization of 0.022 μC cm-2 and a coercive field of 25 kV cm-1. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

收藏

页码：6820 / 6823

页数：4

相关论文

共 42 条

[1] The physics of ferroelectric memories [J].

Auciello, O ;

Scott, JF ;

Ramesh, R .

PHYSICS TODAY, 1998, 51 (07) :22-27

[2] New soft chemical routes to ferroelectric SrBi2Ta2O9 [J].

Babooram, K ;

Ye, ZG .

CHEMISTRY OF MATERIALS, 2006, 18 (02) :532-540

[3] Synthesis and characterization of a family of structurally characterized dysprosium alkoxides for improved fatigue-resistance characteristics of PDyZT thin films [J].

Boyle, TJ ;

Bunge, SD ;

Clem, PG ;

Richardson, J ;

Dawley, JT ;

Ottley, LAM ;

Rodriguez, MA ;

Tuttle, BA ;

Avilucea, GR ;

Tissot, RG .

INORGANIC CHEMISTRY, 2005, 44 (05) :1588-1600

[4] Lanthanide series doping effects in lead zirconate titanate (PLnZT) thin films [J].

Boyle, TJ ;

Clem, PG ;

Tuttle, BA ;

Brennecka, GL ;

Dawley, JT ;

Rodriguez, MA ;

Dunbar, TD ;

Hammetter, WF .

JOURNAL OF MATERIALS RESEARCH, 2002, 17 (04) :871-878

[5]

*BRUK AXS INC, 2000, BRUK SMART SAINT SAD

[6] Single crystal X-ray diffraction studies on [(CH3)nNH4-n]3[Sb2Cl9] (n=2, 3) chloroantimonates(III) in their low-temperature ferroelectric phases -: structures and phase transitions [J].

Bujak, M ;

Angel, RJ .

JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (07) :2237-2246

[7] EUROPIUM THENOYLTRIFLUOROACETONATE PREPARATION AND FLUORESCENCE PROPERTIES [J].

CHARLES, RG ;

OHLMANN, RC .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1965, 27 (01) :255-&

[8] Synthesis and properties of ferroelectric fluoroterpolymers with Curie transition at ambient temperature [J].

Chung, TC ;

Petchsuk, A .

MACROMOLECULES, 2002, 35 (20) :7678-7684

[9] Ferroelectric porous molecular crystal, [Mn3(HCOO)6](C2H5OH), exhibiting ferrimagnetic transition [J].

Cui, HengBo ;

Wang, Zheming ;

Takahashi, Kazuyuki ;

Okano, Yoshinori ;

Kobayashi, Hayao ;

Kobayashi, Akiko .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (47) :15074-15075

[10] Leakage current behavior of SrBi2Ta2O9 ferroelectric thin films on different bottom electrodes [J].

Das, RR ;

Bhattacharya, P ;

Katiyar, RS ;

Bhalla, AS .

JOURNAL OF APPLIED PHYSICS, 2002, 92 (10) :6160-6164

← 1 2 3 4 5 →