Anionic N,O-ligated Pd(II) complexes: highly active catalysts for alcohol oxidation

被引:37
作者
Bailie, David S.
Clendenning, Grainne M. A.
McNamee, Laura
Muldoon, Mark J. [1 ]
机构
[1] Queens Univ Belfast, Ctr Theory & Applicat Catalysis, Sch Chem & Chem Engn, Belfast BT7 1NN, Antrim, North Ireland
关键词
AEROBIC OXIDATION; MOLECULAR-OXYGEN; PALLADIUM COMPLEXES; HYDROGEN-PEROXIDE; AQUEOUS SOLVENTS; LIGAND; MECHANISM; WATER; CONVERSIONS; ACTIVATION;
D O I
10.1039/c0cc01138j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
There is a need to develop effective catalytic methods for alcohol oxidation. Pd(II) complexes have shown great promise as catalysts, however a comparatively small number of ligands have been reported so far. Herein we report the use of commercially available anionic N,O-ligands to produce highly active catalysts.
引用
收藏
页码:7238 / 7240
页数:3
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