Anionic N,O-ligated Pd(II) complexes: highly active catalysts for alcohol oxidation

被引：37

作者：

Bailie, David S.

Clendenning, Grainne M. A.

McNamee, Laura

Muldoon, Mark J. ^{[1
]}

机构：

[1] Queens Univ Belfast, Ctr Theory & Applicat Catalysis, Sch Chem & Chem Engn, Belfast BT7 1NN, Antrim, North Ireland

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 38期

关键词：

AEROBIC OXIDATION; MOLECULAR-OXYGEN; PALLADIUM COMPLEXES; HYDROGEN-PEROXIDE; AQUEOUS SOLVENTS; LIGAND; MECHANISM; WATER; CONVERSIONS; ACTIVATION;

D O I：

10.1039/c0cc01138j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

There is a need to develop effective catalytic methods for alcohol oxidation. Pd(II) complexes have shown great promise as catalysts, however a comparatively small number of ligands have been reported so far. Herein we report the use of commercially available anionic N,O-ligands to produce highly active catalysts.

引用

页码：7238 / 7240

页数：3

共 38 条

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