A comparison study of peach stone and acrylonitrile-divinylbenzene copolymer based activated carbons as chromium(VI) sorbents

被引:72
作者
Duranoglu, Dilek [1 ]
Trochimczuk, Andrzej W. [2 ]
Beker, Ulker [1 ]
机构
[1] Yildiz Tech Univ, Dept Chem Engn, TR-34210 Istanbul, Turkey
[2] Wroclaw Univ Technol, Fac Chem, PL-50370 Wroclaw, Poland
关键词
Activated carbon; Acrylonitrile divinylbenzene; Peach stone; Adsorption; Chromium; AQUEOUS-SOLUTION; HEXAVALENT CHROMIUM; SORPTIVE PROPERTIES; ADSORPTION; SURFACE; REMOVAL; KINETICS; WATER; OPTIMIZATION; ADSORBENTS;
D O I
10.1016/j.cej.2010.08.054
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Two activated carbons were produced by using two different precursor peach stone and acrylonitrile-divinylbenzene copolymer Peach stone based activated carbon was produced by single step steam activation at 800 degrees C polymer based activated carbon was prepared in successive two stages air oxidation at 300 C and final carbonization at 850 C under inert atmosphere Produced carbons showed typical Type 1 nitrogen adsorption isotherms Peach stone based activated carbon has 608 m(2)/g of surface area and 0 331 cm(3)/g of micropore volume while polymer based carbon has 579 m(2)/g of surface area and 0 234 cm(3)/g of micropore volume Boehm s titration results and Fourier transform infrared spectra indicated that the produced carbons possess acidic oxygen functionalities mainly in phenolic form Polymer based activated carbon has 7 12 mmol of nitrogen/g because of the pyridine type groups in the main structure The removal of Cr(VI) from aqueous solutions by activated carbon has been investigated as a function of solution pH The maximum adsorption capacities were obtained at pH 2 in both cases and the maximum capacities were 143 mg/g 83 mg/g and 150 mg/g for peach stone based polymer based and commercial activated carbons respectively The produced carbons could be regarded as potential adsorbents for efficient removal of Cr(VI) from aqueous media (C) 2010 Elsevier B V All rights reserved
引用
收藏
页码:56 / 63
页数:8
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